You can change the URL View's results tables order by clicking the Settings icon at top right -> PRT Settings -> Columns & Sorting.
• Default URLs order by: Set the data order of the URL View. How will the rows (URLs) be ordered?
They can be ordered by Time Added, URL (alphabetically), Group name, or Top Rank, and either ascending or descending.
• Default Terms order by: Set the order of the inner tables (terms) in the URL View.